Liquid-like materials could pave way for new thermoelectric devices

March 26, 2012 // By Julien Happich
In the continual quest for better thermoelectric materials—which convert heat into electricity and vice versa—researchers have identified a liquid-like compound whose properties give it the potential to be even more efficient than traditional thermoelectrics.

The researchers studied a material made from copper and selenium. Although it is physically a solid, it exhibits liquid-like behaviors due to the way its copper atoms flow through the selenium's crystal lattice. "It's like a wet sponge," explains Jeff Snyder, a faculty associate in applied physics and materials science in the Division of Engineering and Applied Science at the California Institute of Technology (Caltech) and a member of the research team. "If you have a sponge with very fine pores in it, it looks and acts like a solid. But inside, the water molecules are diffusing just as fast as they would if they were a regular liquid. That's how I imagine this material works. It has a solid framework of selenium atoms, but the copper atoms are diffusing around as fast as they would in a liquid."

The research, led by scientists from the Chinese Academy of Science's Shanghai Institute of Ceramics in collaboration with researchers from Brookhaven National Laboratory and the University of Michigan, as well as from Caltech, is described in a paper recently published in the journal Nature Materials. A good thermoelectric material must be good at conducting electricity but bad at conducting heat. If it were good at conducting heat, the heat from the hot end would move to the cool end so fast that the whole material would rapidly reach the same temperature. When that happens, the electrons stop flowing.

One way to improve thermoelectric efficiency, then, is to decrease a material's ability to conduct heat. To that end, researchers have been developing thermoelectric materials with a mix of crystalline and amorphous properties, Snyder says. A crystalline atomic structure allows electrons to flow easily, while an amorphous material, such as glass, has a more irregular atomic structure that hinders heat-carrying vibrations from traveling.

These heat-carrying vibrations travel via two types of waves. The first type is a longitudinal or pressure wave, in which