New Li-ion battery design method promises higher energy density

October 26, 2016 // By Nick Flaherty
Researchers at Columbia University ((New York, NY)) have developed a new method to increase the energy density of lithium (Li-ion) batteries by up to a third.

The team, led by Yuan Yang, assistant professor of materials science and engineering at Columbia Engineering, has built a trilayer structure that is stable even in ambient air, which makes the battery both longer lasting and cheaper to manufacture. "When lithium batteries are charged the first time, they lose anywhere from 5-20% energy in that first cycle," said Yang. "Through our design, we've been able to gain back this loss, and we think our method has great potential to increase the operation time of batteries for portable electronics and electrical vehicles."

During the first charge of a lithium battery after its production, a portion of liquid electrolyte is reduced to a solid and coats the negative electrode of the battery, lowering the energy stored by about 10% for today's electrodes, but can reach as high as 20-30% for next-generation negative electrodes with high capacity, such as silicon, because these materials have large volume expansion and high surface area. The large initial loss reduces achievable capacity in a full cell and thus compromises the gain in energy density and cycling life of these nanostructured electrodes.

The traditional approach to compensating for this loss has been to put certain lithium-rich materials in the electrode. However, most of these materials are not stable in ambient air. Manufacturing batteries in dry air, which has no moisture at all, is a much more expensive process than manufacturing in ambient air.

Yang has developed a new trilayer electrode structure to fabricate lithiated battery anodes in ambient air. In these electrodes, he protected the lithium with a layer of the polymer PMMA to prevent lithium from reacting with air and moisture, and then coated the PMMA with such active materials as artificial graphite or silicon nanoparticles. The PMMA layer was then dissolved in the battery electrolyte, thus exposing the lithium to the electrode materials.